Fumigating with phosphine, other fumigants and controlled atmospheres
Grain Fumigation – A Guide
In order to kill grain pests at all stages of their life cycle (egg, larva, pupa, adult), phosphine gas needs to reach, and be maintained at, a concentration possible only in a gas-tight storage.
Key Points
- To control insects at all life stages the only option is to fumigate in a gas-tight storage.
- Cool grain temperatures require a longer fumigation period.
- Aeration fans fitted on gas-tight silos provide a number of benefits including a shorter ventilation period following a fumigation.
The total time required for effective fumigation ranges from 10–17 days, accounting for the minimum exposure period, ventilation and withholding period. This highlights the importance of monitoring grain regularly and at least 17 days before out-loading to allow sufficient time to fumigate if required.
Avoid Exposure: Wearing full Personal Protective Equipment (PPE), work with phosphine in an open, well-ventilated area with the wind coming from the side.
Rates for success
When determining how much phosphine to apply, it is important to treat the entire storage volume, regardless of how much grain is contained inside. For example, a 100 tonne silo full of grain requires 200 phosphine tablets. If that same 100t silo is only half full of grain, it still requires 200 phosphine tablets for effective fumigation.
Handle with care
Phosphine is a highly toxic gas with potentially fatal consequences if handled incorrectly. As a minimum requirement, the label directs the use of cotton overalls buttoned at the neck and wrist, eye protection, elbow-length PVC gloves and a breathing respirator with combined dust and gas cartridge.
Where to apply
Arrange the tablets where as much surface area as possible is exposed to air, so the gas can disperse freely throughout the grain stack. Spread phosphine tablets evenly across trays before hanging them in the head space or placing them level on the grain surface inside a gas-tight, sealed silo. Hang bag chains in the head space or roll out flat on the top of the grain so air can freely pass around them as the gas dissipates. Bottom-application facilities must have a passive or active air circulation system to carry the phosphine gas out of the confined space as it evolves. Without air movement, phosphine can reach explosive levels if left to evolve in a confined space.
Time to kill
To control pests at all life stages and prevent insect resistance, phosphine gas concentration needs to reach 300 parts per million (ppm) for seven days (when grain is above 25°C) or 200ppm for 10 days (between 15–25°C). Insect activity is slower in cooler grain temperatures so require longer exposer to the gas to receive a lethal dose.
Table 1 – Application rates for phosphine tablets in storage
Gas venting
Following fumigation, ventilate silos so grain can be delivered free from harmful gas residues. With tablet residue or bag chains removed, leave silos open for no less than five days, or no less than one day with aeration fans
operating. The final step is to hold grain for a further two days after ventilation before using for human consumption or stockfeed
Disclaimer
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CAUTION: RESEARCH ON UNREGISTERED PESTICIDE USE
Any research with unregistered pesticides or of unregistered products reported in this document does not constitute a recommendation for that particular use by the authors or the authors’ organisations. All pesticide applications must accord with the currently registered label for that particular pesticide, crop, pest and region. Copyright © All material published in this Fact Sheet is copyright protected and may not be reproduced in any form without written permission from the GRDC.